マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2006/05
形態種別	研究論文（学術雑誌）
査読	査読あり
標題	Three-dimensional coordination polymer of silver(I) with bridging ligand hexakis(4-pyridyl) [3]radialene
執筆形態	共著
掲載誌名	Crystal Growth & Design
掲載区分	国外
出版社・発行元	ACS publication
巻・号・頁	6(5),pp.1083-1085
総ページ数	3
著者・共著者	◎Kouzou Matsumoto, Yukako Harada, Nao Yamada, Hiroyuki Kurata, Takeshi Kawase, Masaji Oda
概要	This paper describes the synthesis of hexakis(4-pyridyl)[3]radialene and the crystal structures of its complexes. The title compound formed a complex with two molecules of resorcinol. In this complex, the double hydrogen bonding between the title compound and resorcinol is observed. A silver(I) complex of the title compound was also obtained as reddish crystals. Notably, the crystal structure of the silver(I) complex features a three-dimensional coordination polymer. The composition of the crystal is 1:1 with respect to the title compound and silver(I) atoms including the solvent molecules of one DMSO and one methanol. Four of the six nitrogen atoms are coordinated to the silver(I) atom and the other two pyridyl groups are free from coordination. The coordination geometry of the silver(I) atom is distorted tetrahedral. To the best of our knowledge, this is the first example of a three-dimensional coordination polymer of a [3]radialene-based bridging ligand.
DOI	10.1021/cg060073f