マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2017/09
形態種別	速報，短報，研究ノート等（学術雑誌）
査読	査読あり
標題	2-[Tris(pyridine-2-yl)methyl]pyridinium trans-bis(acetonitrile)tetrachlororuthenate(III) acetonitrile monosolvate
執筆形態	共著
掲載誌名	IUCrData
掲載区分	国外
出版社・発行元	International Union of Crystallography
巻・号・頁	2(9),pp.x171371
総ページ数	3
担当区分	筆頭著者,責任著者
著者・共著者	◎Kouzou Matsumoto, Masaki Kannami, Masaji Oda
概要	The asymmetric unit of the title compound, [(C5H4N)3C(C5H5N)][RuCl4 (CH3CN)2]CH3CN, contains one 2-[tris(pyridin-2-yl)methyl]pyridinium cation, one trans-bis(acetonitrile)tetrachloridoruthenate(III) anion and one acetonitrile solvent molecule. The RuIII ion is coordinated by four Cl anions in the equatorial plane and by two acetonitrile ligands in the axial positions, forming a distorted octahedral geometry. The cation, the monoprotonated species of tetrakis(pyridin-2-yl)methane, forms an intramolecular N—H N hydrogen bond between the pyridinium ring and one of the pyridine rings. The complex anions are linked to each other via C—H Cl hydrogen bonds, forming an undulating sheet parallel to the ac plane. A C—H N hydrogen bond between the cation and the anion is also observed.