マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2015/12
形態種別	研究論文（学術雑誌）
査読	査読あり
標題	Synthesis, Molecular Structrure, and Morphological Properties of dendritic tetra-2-thienylmethane
執筆形態	共著
掲載誌名	Heterocycles
掲載区分	国内
出版社・発行元	The Japan Institute of Heterocyclic Chemistr
巻・号・頁	91(12),pp.2343-2353
総ページ数	11
著者・共著者	◎Kouzou Matsumoto, Sota Kugo, Takeshi Suzuki, Daisuke Takajo, Akira Inaba, Yasukazu Hirao, Hiroyuki Kurata, Takashi Kubo
概要	Tetrakis(5-(tri-2-thienyl)methyl-2-thienyl)methane, in which as many as 16 thiophene rings connected with five sp3 carbon atoms, has been synthesized from tetra-2-thienylmethane in four steps. This compound can take both crystalline and glass state. Although a deformed structure is taken in the crystal, but it turns to be a metastable state. The second polymorph exhibits the melting point more than 30 oC higher than that of the metastable state, suggesting the effective intermolecular interaction.
DOI	10.3987/COM-15-13337