マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2014/03
形態種別	速報，短報，研究ノート等（学術雑誌）
査読	査読あり
標題	Bis[tetrakis(pyridine-2-yl)methane-3N,N’,N’’]cobalt(II) tetrakis(thiocyanato-N)cobaltate(II) methanol monosolvate
執筆形態	共著
掲載誌名	Acta Crystallographica Section E
掲載区分	国外
出版社・発行元	International Union of Crystallography
巻・号・頁	70(3),pp.m96-m97
総ページ数	2
著者・共著者	Yuya Tsunezumi, Kouzou Matsumoto, Shinya Hayami, Akira Fuyuhiro, Satoshi Kawata
概要	The title complex, [Co(C21H16N4)2][Co(NCS)4]·CH3OH, consists of one [Co{C(py)4}2]2+ complex cation [C(py)4 = tetra­kis­(pyridin-2-yl)methane], one [Co(NCS)4]2− complex anion and a methanol solvent mol­ecule. In the cation, the CoII atom is coordinated by six N atoms of two C(py)4 ligands in a distorted octa­hedral geometry. In the anion, the CoII atom is coordinated by the N atoms of four NCS− ligands in a distorted tetra­hedral geometry. The methanol mol­ecule is disordered and was modelled over three orientations (occupancies 0.8:0.1:0.1). There are two weak hydrogen-bond-like inter­actions between the methanol solvent mol­ecule and NCS− ligands of the anion [O⋯S = 3.283 (3) and 3.170 (2) Å].
DOI	10.1107/S160053681400289X