マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2012/12
形態種別	研究論文（学術雑誌）
標題	Singlet Open-Shell Character of Conjugated Kekule Molecules
執筆形態	共著
掲載誌名	AIP Conference Proceeding
掲載区分	国外
出版社・発行元	American Institute of Physics
巻・号・頁	1504,pp.883-886
総ページ数	4
著者・共著者	Takashi Kubo, Mitsuya Aoba, Akihiro Shimizu, Yasukazu Hirao, Kouzou Matsumoto, Hiroyuki Kurata, Masayoshi Nakano
概要	We have studied the properties of singlet open-shell molecules that are designed, synthesized, and isolated by us. The molecules contain p-quinodimethane or cumulene structures in the middle of their skeletons, and also equip spindelocalizing moieties, phenalenyl, in the both ends for thermodynamic stabilization. Crystal structures and electronic spectra revealed that these conjugated Kekulé molecules actually had open-shell character despite closed-shell chemical structures can be drawn for the compounds.
DOI	10.1063/1.4771836