マツモト　コウゾウ   MATSUMOTO Kouzou   松本 幸三    所属   専修大学  経営学部    職種   教授
言語種別	英語
発行・発表の年月	2012/01
形態種別	研究論文（学術雑誌）
査読	査読あり
標題	Synthesis, Electronic, and Morphological Properties of Tetrahedral Oligothiophenes with n-Hexyl Terminal Groups
執筆形態	共著
掲載誌名	Chemistry an Asian Journal
掲載区分	国外
出版社・発行元	Wiley-VCH
巻・号・頁	7(1),pp.225-232
総ページ数	8
著者・共著者	◎Kouzou Matsumoto, Sota Kugo, Daisuke Takajo, Akira Inaba, Yasukazu Hirao, Hiroyuki Kurata, Takeshi Kawase, Takashi Kubo
概要	A series of tetrahedral oligothiophenes bearing n-hexyl groups at the alpha-positions of the terminal thiophene rings, (n-C6H13(C4H2S)n)4C (n=1–4), has been synthesized. Whereas the smaller derivatives (n=1, 2) were obtained as liquid substances, the larger derivatives (n=3, 4) were obtained as solids. Hex-T3TM not only appeared in the crystalline state but also the amorphous state, which was stable to up to 80 oC. Interactions between terthiophene branches was also suggested in the radical cations of Hex-T3TM by cyclic voltammetry measurements.
DOI	10.1002/asia.201100639