エハラ タカシ
Takashi Ehara
惠原 貴志 所属 石巻専修大学 人間学部 職種 教授 |
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言語種別 | 英語 |
発行・発表の年月 | 2016/02 |
形態種別 | 研究論文(学術雑誌) |
査読 | 査読あり |
標題 | Preparation of CuYO2 Thin Films by Sol-Gel Method Using Copper Acetate and Yttrium Acetate as Metal Sources |
執筆形態 | 単著 |
掲載誌名 | Thin Film Technology and Applications, Scientific research publishing |
巻・号・頁 | 4,pp.24-28 |
総ページ数 | 5 |
概要 | Delafossite structured p-type wide bandgap semiconductor, CuYO2 thin films were prepared on
SiO2 substrate by sol-gel method using copper (II) acetate and yttrium (III) acetate as source materials. The films preparation process was studied by varying annealing temperature after the preparation of gel films by spin coating, followed by thermal annealing at higher temperature. In the present work, one step annealing directly from Cu-Y-gel under nitrogen flow was used. X-ray diffraction (XRD) revealed that the film annealed at 800 ̊C is significantly c-axis oriented, shows only (002) and (004) peaks at 15.6 ̊ and 31.5 ̊, respectively. The optical bandgap of 3.7 - 3.8 eV is estimated by (αhν)2 plot which is higher than previous works. In addition, the films with highly c-axis orientation showed photoluminescence (PL) at room temperature with very broad peak at 2.3 eV. The films annealed at different temperature showed different structural properties. |
DOI | http://dx.doi.org/10.4236/msce.2016.41005 |