マエダ　トシテル   Toshiteru Maeda   前田　敏輝    所属   石巻専修大学  理工学部    職種   教授
言語種別	英語
発行・発表の年月	1997/11
形態種別	未選択
標題	In-situ SERS Study of Water Molecules on a Silver Electrode in Alkali-hydroxide Solutions
執筆形態	その他
掲載誌名	Surface Science
巻・号・頁	389(1-3),pp.212
総ページ数	11
概要	In situ surface enhanced Raman has been used to study water molecules adsorbed on a silver electrode in 0.5 M alkali-hydroxide aqueous solutions. Raman spectra and cyclic voltammograms were measured simultaneously while the electrode potential was swept continuously. The alkali-hydroxide solutions were LiOH, NaOH, KOH and CsOH. Raman lines associated with water molecules are identified by a comparison with those obtained for aqueous solutions with D2O instead of H2O. Strong Raman lines, which are associated with the existence of oxygen species adsorbed on silver electrode, were observed in a limited region of electrode potential. The variation of Raman intensities of water molecules, when the electrode potential is scanned, is discussed in terms of the different roles of the cations of the respective alkali-hydroxide solutions.
DOI	10.1016/S0039-6028(97)00415-9